5-Bromo-3-cyclohexylsulfinyl-2,7-dimethyl-1-benzofuran
نویسندگان
چکیده
In the title compound, C(16)H(19)BrO(2)S, the cyclo-hexyl ring adopts a chair conformation. In the crystal, mol-ecules are linked by a Br⋯Br [3.5994 (5) Å] contact and a C-H⋯π inter-action involving the phenyl ring of the benzofuran. The crystal structure also exhibits a slipped π-π inter-action between the furan rings of neighbouring mol-ecules [centroid-centroid distance = 3.767 (1) Å and inter-planar distance of 3.452 (1) Å with a slippage of 1.508 Å].
منابع مشابه
5-Chloro-3-cyclohexylsulfinyl-2,7-dimethyl-1-benzofuran
In the title compound, C(16)H(19)ClO(2)S, the cyclo-hexyl ring adopts a chair conformation and the aryl-sulfinyl unit is positioned equatorial relative to the cyclo-hexyl group. The least-squares plane through all six C atoms of the cyclo-hexyl ring makes a dihedral angle of 74.80 (6)° with the mean plane of the benzofuran fragment. In the crystal, mol-ecules are linked through inter-molecular ...
متن کامل5-Bromo-3-(4-fluorophenylsulfinyl)-2,7-dimethyl-1-benzofuran
In the title compound, C(16)H(12)BrFO(2)S, the 4-fluoro-phenyl ring makes a dihedral angle of 83.29 (5)° with the mean plane of the benzofuran fragment. In the crystal, mol-ecules are linked by weak inter-molecular C-H⋯O hydrogen bonds.
متن کامل5-Bromo-3-cyclohexylsulfonyl-2,7-dimethyl-1-benzofuran
In the title compound, C(16)H(19)BrO(3)S, the cyclo-hexyl ring adopts a chair conformation. In the crystal, mol-ecules are linked through weak C-H⋯O hydrogen bonds and Br⋯O contacts [3.211 (1) Å].
متن کامل5-Bromo-3-(4-fluorophenylsulfonyl)-2,7-dimethyl-1-benzofuran
In the title compound, C(16)H(12)BrFO(3)S, the 4-fluoro-phenyl ring makes a dihedral angle of 72.35 (5)° with the mean plane [r.m.s. deviation = 0.008 (1) Å] of the benzofuran fragment. In the crystal, mol-ecules are linked into [010] chains via two different inversion-generated pairs of C-H⋯O hydrogen bonds. The crystal structure also exhibits slipped π-π inter-actions between the benzene ring...
متن کامل5-Bromo-2,7-dimethyl-3-methylsulfinyl-1-benzofuran
In the title compound, C(11)H(11)BrO(2)S, the O atom and the methyl group of the methyl-sulfinyl substituent are located on opposite sides of the plane of the benzofuran fragment. The crystal structure is stabilized by non-classical inter-molecular C-H⋯O hydrogen bonding, and by inter-molecular C-Br⋯π inter-actions, with C-Br⋯Cg = 3.629 Å (Cg is the centroid of the benzene ring). In addition, t...
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